English
聯系我們
網站地圖
郵箱
舊版回顧



上海硅酸鹽所在鋰電池安全性提升研究中取得進展

文章來源:上海硅酸鹽研究所   發布時間:2019-05-10  【字號:     】  

  最近,中國科學院上海硅酸鹽研究所研究員溫兆銀團隊通過離子導電型引發劑實現了凝膠聚合物電解質的原位制備,該凝膠聚合物電解質具有優異的耐火性能,基于該電解質組裝的固態鋰電池在同時承受剪切與火燒條件(火焰溫度528)下仍能為發光二極管陣列供電,使鋰電池的安全性大大提高。相關工作申請了中國發明專利,主要研究結果以In Situ Generated Fireproof Gel Polymer Electrolyte with Li6.4Ga0.2La3Zr2O12 As Initiator and Ion-Conductive Filler 為題發表在國際期刊《先進能源材料》(Advanced Energy Materials上,論文第一作者為上海硅酸鹽所在讀博士研究生徐東,導師為溫兆銀。

  凝膠聚合物電解質(GPE)在一定程度上兼具固態聚合物電解質(SPE)的高安全性與液態電解質高離子電導率的優點,被認為是當前最適合實際應用的一種電解質體系。目前研究較多的是基于聚偏氟乙烯(PVDF)及其衍生物的凝膠聚合物電解質體系。然而凝膠電解質中仍然含有一定量的可燃性液態電解質,存在安全隱患。為進一步提高其安全性能以及電化學性能,科研工作者做了大量的研究工作,主要包括有機-有機共混改性、有機-無機復合改性、物理/化學交聯改性等。但大多數文獻并未對凝膠聚合物電解質的安全性能進行詳細報道。另一方面,在目前常用的相轉換法等凝膠聚合物電解質的制備過程中,使用了大量揮發性有機溶劑,既污染環境,又增加成本,且制備過程繁瑣。采用原位交聯聚合制備的方法可以避免或減輕上述問題。

  溫兆銀團隊以石榴石型固體電解質(Li6.4Ga0.2La3Zr2O12)為引發劑和離子導電型填料,在聚偏氟乙烯-六氟丙烯共聚物(PVDF-HFP)的磷酸三乙酯/氟代碳酸乙烯酯(TEP/FEC)混合溶液中引發PVDF-HFP的脫氟和交聯過程,從而實現凝膠聚合物電解質的原位制備,并對凝膠轉變過程的機理進行了深入研究。優化后的凝膠聚合物電解質在20時離子電導率達到1.83×10-3 S cm-1,室溫下電化學穩定窗口4.75V。該凝膠聚合物電解質具有優異的耐火性能,由其組裝的固態鋰電池具有較高的安全性。基于該凝膠聚合物電解質的三元鋰電池表現出較好的循環穩定性。該工作提供了采用防火型凝膠電解質可獲得優良的離子電導率以及保證凝膠聚合物電解質和相應鋰電池高安全性的研究新思路。

  相關工作得到國家重點研發計劃、國家自然科學基金面上項目的資助。

  論文鏈接

 

  防火型凝膠聚合物電解質組成與結構示意圖及基于該凝膠聚合物電解質的軟包鋰電池的剪切和燃燒實驗




(責任編輯:葉瑞優)

附件:

專題推薦

相關新聞


© 1996 - 中國科學院 版權所有 京ICP備05002857號  京公網安備110402500047號  聯系我們

地址:北京市三里河路52號 郵編:100864

彩82www.c6313.com www.655811.com | www.639324.com | www.022456.com | www.td47.com | 18768.com | www.666108.com | www.395911.com | www.285988.com | www.37075.com | www.33.vip | 796034.com | 543022.com | 110876.com | 686087.com | 017466.com | 50999.com | www.981648.com | 886716.com | 393398.com | 949325.com | 232552.com | www.ai71.cc | 彩61www.055890.com | 62484.cc | 368906.com | www.15pj.cc | 759027.com | www.9491.top | www.1944.xyz | www.2498.in | www.215.date | www.611773.com | www.625647.com | www.661836.com | www.691990.com | www.707091.com | www.652999.com | www.779134.com | www.698951.com | www.641616.com | www.817805.com | www.768326.cc | www.707713.com | www.930108.com | www.791814.com | www.702086.com | www.710912.com | www.762241.com | www.814323.com | www.751421.com | www.729589.com | www.678154.com | www.499951.com | www.629826.com | www.947574.com | www.956983.com | www.925080.com | 869845.com | 959407.com | 111067.com | 130764.com | 712394.com | m.ko09.com | 976614.com | 355483.com | 651493.com | 870782.com | 220256.com | 670471.com | 259635.com | 345935.com | 787585.com | www.907771.com | www.664350.com | www.870762.com | 452590.com | 815424.com | 751434.com | 221372.com | 949641.com | 269908.com | 241099.com | 3739.biz | liuhcai810885.com | 026730.com | 083109.com | 910410.com | 509823.com | www.915275.com | www.774792.com | www.875616.com | 7025.biz | 127039.com | www.969184.com | 40cp.com | 彩票大家乐www.21202n.com | 500彩票www.652982.com | www.zj55.cc | www.26pw.com | www.62aq.com | www.199.in | www.83036.com | www.121453.com | www.231200.cc | www.314540.com | www.761249.com | www.814178.com | www.971352.com | www.976676.com | 237141.com | www.wq5.cc | www.3638.net | www.4185.com | www.e37.net | 607012.com | 118彩票www.62118b.com | www.39sx.com | www.576498.com | www.630689.com | www.881206.com | 024573.com | www.982351.com | www.886406.com | 554658.com--70435.com | www.981865.com | www.869626.com | www.927228.com | 45mj.com | 289448.com | www.990391.com | www.929099.com | www.812244.com | www.855701.com | www.988876.com | 131464.com | www.971241.com | www.955799.com | www.868708.com | www.963612.com | www.872029.com | www.872323.com | www.853390.com | www.813624.com | www.747490.com | www.603197.com | www.590901.com | www.531662.com | www.532582.com | www.433350.com | www.527599.com | www.400023.com | www.562943.com | www.554545.com | www.310932.com | www.255197.com | www.293525.com | www.246328.com | www.149369.com | www.165833.com | www.189311.com | www.127710.com | www.195211.com | www.123264.com | www.87397.com | www.85613.cc | www.18110.cc | www.0247.hk | www.2935.cc | www.91tr.com | www.00md.com | www.fg1.cc | GO彩www.wo41.com | www.068339.com | 758074.com | 837461.com | 964648.com | 384808.com | kj83.cc | 4067.com | www.923718.com | www.808872.com | www.879400.com | www.953254.com | www.793127.com | 206633.com | www.60ga.com | www.j74.club | www.di09.com | www.ve44.com | www.zj.cc | 330711.com | 626018.com | 169847.com | 731019.com | 028038.com | www.976224.com | www.868911.com | www.801841.com | www.697799.com | www.584433.com | www.450661.com | www.350519.com | www.312523.com | www.222259.com | www.118447.com | www.99640.com | www.88414.com | www.22337.com | www.6656.cn | www.5906.vip | www.56qu.com | www.un36.com | www.ap00.com | 425753.com | 443719.com | 655877.com | 951481.com | www.761111.com | 724222.cc | 524572.com | 621155.com | 7hw.cc | www.984000.cc | www.888903.com | www.749679.com | www.646424.com | www.670730.com | www.567178.com | www.439653.com | www.908241.com | www.410789.com | www.61nv.com | www.771222.com | www.51664.com | 375921.com | www.290140.com | www.cp329.com | www.580917.com | www.76ri.com | www.783993.com | www.64419.com | 262593.com | www.466730.com | www.06cx.com | www.707383.com | www.15318.cc | www.956829.com | www.025628.com | 071811.com | www.259962.com | www.fo95.com | www.762519.com | www.999655.com | 219017.com | vn98.com | 958061.com | 091031.com | 475302.com | www.gx26.com | www.4de.cc | www.02112.com | www.381511.com | www.479179.com | www.603152.com | www.630522.com | www.122354.com | www.du14.com | www.661041.com | www.8219.loan | www.957086.com | www.196038.com | 097368.com | www.431921.com | www.560011.com | www.447370.com | www.378288.com | www.298697.com | www.290268.com | www.073106.com | www.019370.com | www.57755.cc | www.10782.com | www.4829.xyz | www.zr99.com | 500彩票网www.810337.com | 200573.com | 950357.com | 756757.com | 2078.com | 40666.com | www.917497.com | www.773201.com | www.641558.com | www.796140.com | www.607186.com | www.459959.com | www.310052.com | www.175715.com | www.096865.com | www.60664.com | www.39282.cc | www.25219.cc | www.4999.site | www.09od.com | www.wp3.com | 福彩www.16878y.com | 077058.com | 841189.com | www.964670.com | www.804409.com | www.703188.com | www.539769.com | www.368830.com | www.343411.com | www.273518.com | www.100334.com | www.89969.com | www.6726.com | www.68yh.com | www.1231.net | www.3903.vip | www.49bm.com | www.lg46.com | www.cai3930.com | 300793.com | 203638.com | fm88.cc | 720627.com | 7459.com | www.954308.com | www.410422.com | www.089138.com | www.107167.com | www.087873.com | www.311656.com | www.453382.com | www.859825.com | www.41lo.com | www.t58.tv | www.pn24.com | www.29om.com | www.75gq.com | www.12634.com | www.36504.com | www.1853.biz | www.9457.top | www.5459.vip | www.96yn.com | www.5927.cn | www.76yk.com | 大赢家彩票网www.636121.com | 195929.com | 4974.biz | www.908987.com | www.637868.com | www.669527.com | www.332757.com | www.368677.com | www.35595.cc | www.980589.com | www.033620.com | 903328.com | www.966106.com | www.vf26.com | www.645338.com | www.1145.me | www.987623.com | www.180671.com | www.039255.com | 604448.com | www.9qx.com | www.90dw.com | www.48881.com | www.96237.com | www.65526.cc | www.054776.com | www.007147.cc | www.95281.com | www.66929.cc | www.006854.com | www.200020.cc | www.238816.com | www.206206.cc | www.151412.com | www.298042.com | www.267512.com | www.559032.com | www.567639.com | www.573130.com | www.562585.com | www.594822.com | www.516975.com | www.680597.com | www.632629.com | www.673126.com | www.661013.com | www.678713.com | www.971239.com | www.964850.com | www.888007.com | www.930565.com | 550994.com | 071636.com | 705032.com | 211082.com | www.965764.com | www.879721.com | www.839286.com | www.848657.com | www.973337.com | www.898636.com | www.781142.com | www.927687.com | www.938332.com | www.844547.com | www.909209.com | www.865368.com | www.852078.com | www.806128.com | www.799675.com | www.730978.com | www.739848.com | www.784591.com | www.678615.com | www.671428.com | www.594166.com | www.536407.com | www.647200.com | www.821215.com | www.736668.com | www.666726.com | www.553363.com | www.405448.com | www.652309.com | www.750750.cc | www.649837.com | www.683995.com | www.586125.com | www.541017.com | www.573876.com | www.501217.com | www.388071.com | www.635251.com | www.774077.com | www.658922.com | www.665014.com | www.639049.com | www.694896.com | www.617148.com | www.620912.com | www.650698.com | www.659531.com | www.740818.com | www.712289.com | www.606396.com | www.495707.com | www.629735.com | www.722276.com | www.631695.com | www.637411.com | www.680879.com | www.635489.com | www.947841.com | www.799606.com | www.969227.com | www.849980.com | www.996643.com | www.890791.com | www.755643.com | www.826311.com | 373453.com | 784422.com | www.961557.com | www.838494.com | www.888252.com | www.796648.com | 511633.com | www.dk1.cc | 8号彩票www.81520q.com | www.994160.com | 267327.com | 815297.com | 492404.com | 福彩www.26878m.com | www.fq13.com | www.850.gg | www.1043.in | www.9697.biz | www.2796.net | www.0240.me | www.3814.in | www.83mo.com | www.11dj.com | www.qk07.com | www.io03.com | www.ua64.com | www.pk0.cc | www.30ij.com | www.ln68.com | www.cp627.com | 百姓彩票www.bxcp3.com | 944518.com | www.50702.com | www.51319.cc | www.06599.cc | www.1256.tv | www.03938.com | www.3649.cn | www.8609.vip | www.94at.com | www.6469.vip | www.54fh.com | www.lt06.com | www.mq97.com | www.cp1228.com | 656625.com | 13862.com | 615951.com | 963087.com | 953075.com | www.982376.com | 893736.com | www.950938.com | www.792058.com | www.640448.com | www.781330.com | www.632988.com | www.628527.com | www.768228.com | www.655354.com | www.713567.com | www.586153.cc | www.488696.com | www.353049.com | www.203056.com | www.095528.com | www.85299.cc | www.9202.online | www.98in.com | www.80xz.com | www.uf96.com | 500彩票网www.65707t.com | 733843.com | 237746.com | www.96hn.com | www.84es.com | www.um74.com | www.cw89.com | 网易彩票www.9356n.com | 149451.com | 797827.com | 554180.com | www.854447.com | www.645362.com | www.366289.com | www.101701.com | www.wo87.com | www.764900.com | www.324391.com | www.76uk.com | www.721234.cc | www.41770.com | www.ot48.com | www.610292.com | www.913250.com | www.501965.com | www.wc28.com | www.912299.com | www.464699.com | www.5ct.com | www.670290.com | www.0133.wang | 天地彩www.4tdc.com | www.686856.com | www.162922.com | www.088549.com | www.8558.net | www.886327.com | www.819698.com | www.221510.com | 087084.com | www.332221.com | www.84200.com | www.ed39.com | www.772171.com | www.566658.com | www.267252.com | www.pq22.com | www.983608.com | www.480274.com | www.pm47.com | www.727332.com | www.223773.com | www.cp981.com | 417448.com | www.677845.com | www.239558.com | 939583.com | www.904083.com | www.138742.com | www.cai527.com | www.640424.com | www.375251.com | www.9198.loan | 大赢家彩票平台www.689169.com | www.972463.com | www.335635.com | www.cn26.com | 625857.com | www.220826.com | 736515.com | www.543054.cc | www.131836.com | 亚洲彩票联盟www.838669.com | www.974215.com | www.567568.com | www.059593.com | cai7722.com | www.823247.com | www.53558.cc | www.984052.com | www.128953.com | www.43138.com | 132810.com | www.771145.com | www.303051.com | www.2254.cc | www.902955.com | www.852691.com | www.004342.com | 88053.com | www.860661.com | www.157961.com | www.8977.net | 68彩票www.68682k.com | www.885965.com | www.995389.com | www.029745.com | 671446.com | www.100779.com | 739641.com | www.988138.com | www.061222.com | www.60yr.com | 624656.com | www.834454.com | www.917923.com | www.732665.com | www.540906.com | www.279533.com | www.142726.com | www.052066.com | www.53432.com | www.02008.com | www.85hg.cc | 795428.com | www.855800.cc | www.133534.com | www.3789.vip | www.952748.com | www.907625.com | www.83821.cc | www.vr50.com | www.751340.com | www.3825.in | www.680613.com | www.553959.com | www.685201.com | www.539134.com | www.322844.com | www.133842.com | www.83933.com | www.50026.com | www.520.biz | www.04wd.com | 700733.com | www.344387.com | 凤凰彩票www.77802p.com | www.383195.com | www.lk24.com | www.554960.com | www.we74.com | www.535952.com | www.xx16.com | www.546254.com | www.67ql.com | www.671136.com | www.779226.com | www.625659.com | www.535832.com | www.343665.com | www.176500.com | www.020495.com | www.26755.cc | www.1408.online | www.080.me | www.2981.com | www.0br.com | 鑫彩网www.xcw866.com | 069244.com | 092690.com | www.992797.com | www.859947.com | www.066721.com | 304578.com | www.129643.com | 97789.com | www.352596.com | 553759.com | www.365840.cc | www.tb02.com | www.586628.com | www.m13.cc | www.609525.com | www.87cc.cc | www.711900.com | www.600.hk | www.814199.com | www.6787.vip | www.803759.com | www.69592.com | 346969.com | www.089157.com | jv06.com | www.081092.com | 947872.com | www.093636.com | 714416.com | www.108100.com | 840329.com | www.101687.com | 751664.com | www.179394.com | 512138.cc | www.335945.com | www.981470.com | www.94446.cc | 656089.com | www.327398.com | www.85xb.com | 839087.com | www.329308.com | www.10638.com | www.cp7782.com | www.840902.com | www.216817.com | www.4273.biz | www.792999.com | www.15234.cc | www.837664.com | www.66277.com | 765542.com | www.185478.com | www.am82.cc | www.444963.com | www.64ro.com | 171199.com | www.200029.com | 167731.com | www.196102.com | 31ey.com | www.457167.com | www.73295.com | 869020.com | www.092256.com | 932145.com | www.076633.com | 中国彩票网www.zg39.com | www.877073.com | www.276312.com | www.7875.pw | 959115.com | www.708383.com | www.8289.in | 173505.com | www.458016.com | www.oj12.com | www.608319.com | www.23ww.com | www.818033.com | www.387148.com | www.er36.com | www.513098.com | www.3578.vip | 518022.cc | www.358346.com | www.056228.com | www.x20.top | www.775553.com | www.789278.cc | www.866019.com | www.812082.com | www.636349.com | www.160793.com | www.7846.shop | 424969.com | www.864872.com | www.682707.com | www.0856.in | 540815.com | www.822399.com | www.043037.com | 3550.biz | www.024477.com | www.t20.website | www.790339.com | www.7492.vip | www.795470.com | www.5233.in | 951009.com | www.875226.com | www.324236.com | 福彩网www.5522a.cc | www.883790.com | www.332029.com | 彩82www.290038.com | www.550047.com | www.73ls.com | 091166.com | www.204196.com | 607648.com | www.254026.com | www.cai5558.com | 567242.com | www.603635.com | www.089692.com | 350803.com | www.826708.com | www.6677.me | www.874525.com | www.321234.cc | www.59nq.com | 775467.com | www.566043.com | www.308024.com | 众彩www.658960.com | www.738001.com | www.1hn.cc | www.672289.com | www.87764.com | www.0029.site | 949069.com | www.647611.com | www.268650.com | www.7dj.com | www.683212.com | www.153615.com | 966563.com | www.324987.com | 456549.com | www.308755.com | 30301.cc | www.503330.com | www.021333.com | www.mt95.com | 1168.pw | www.112296.com | www.tx19.cc | 80281.com | www.630860.com | www.258232.com | www.938.cn | 420056.com | www.719615.com | www.202053.com | www.uj3.cc | www.644378.com | www.110473.com | www.cp8466.com | www.413800.com | www.4053.xyz | 578052.com | www.646641.com | www.251208.com | www.5033.cm | www.988308.com | www.100413.com | www.r66.biz | www.657607.com | www.9099.cm | 487365.com | www.529381.com | www.a90.net | 359950.com | www.552093.com | www.397964.com | www.131446.com | 968457.com | www.338287.com | www.89qo.com | www.879659.com | www.28635.cc | www.836787.com | www.15655.cc | www.834485.com | www.93397.cc | www.hp23.com | www.703257.com | www.257672.com | www.5827.wang | 449945.com | www.210866.com | www.099506.com | 045104.com | www.073724.com | 032393.com | 965164.com | 545849.com | www.790902.com | www.2380.cm | www.731811.com | www.77ds.com | www.592810.com | www.5uw.com | www.ui23.com | 151370.com | 139797.com | 941903.com | www.865897.com | www.711026.com | www.447227.com | www.181497.com | www.084044.com | www.05991.com | www.22.cn | 梦想彩票站www.43131h.com | 314635.com | www.862065.com | www.639204.com | www.656749.com | www.385892.com | www.177125.com | www.113061.com | www.12973.cc | www.x96.com | 997479.com | 368847.com | iz11.com | www.933200.com | www.638127.com | www.756591.com | www.491616.com | www.9087.org | www.773332.com | www.85dg.com | www.609372.com | www.9938.in | www.816582.com | www.886677.com | www.121759.com | 969033.com | www.059170.com | www.986559.com | www.47539.com | 02885.com | www.017895.com | www.974040.com | www.36077.cc | www.836242.com | www.2523.xyz | www.62yd.com | 595380.com | www.760327.com | www.4614.vip | www.708518.com | www.188126.com | 7097.com | www.103981.com | 2884.biz | www.94168.com | www.947568.com | www.06460.com | www.801962.com | www.1151.me | www.797913.com | www.1251.cn | www.778197.com | www.2333.tv | www.974795.com | www.197597.com | 136743.com | www.108725.com | 162829.com | www.96816.cc | www.919778.com | www.08330.com | 902352.com | www.041255.com | www.988578.com | www.39729.cc | www.851776.com | www.8556.cn | www.803963.com | www.2222.cm | www.695485.com | www.37du.com | www.596763.com | www.07ki.com | www.544483.com | www.xb8.com | www.377687.com | www.ud34.com | www.562025.com | www.wm09.com | www.530005.com | www.at28.com | www.369406.com | E彩堂www.43818r.com | www.336381.com | 785346.com | www.265782.com | 101755.com | www.146342.com | 504747.com | www.110797.com | 525065.com | www.023481.com | 019745.com | www.84306.com | www.507822.com | www.168935.com | www.08981.com | 大赢家彩票平台www.955484.com | www.965441.com | www.506646.com | www.108389.com | www.67nl.com | 312770.com | www.830670.com | www.557855.com | www.083357.com | www.38fs.com | 848504.com | www.629070.com | www.287275.com | www.193977.com | www.52825.com | www.25ef.com | 751703.com | www.685056.com | www.248336.com | www.15288.com | 奔驰彩票www.281566.com | www.936956.com | 5238.biz | 701901.com | www.753268.com | www.282892.com | www.05998.cc | 千百万彩票www.qbwc5.com | www.979413.com | www.638768.com | www.251777.com | www.012315.com | www.na76.com | 242356.com | www.637050.com | www.226556.com | www.0268.net | 156114.com | www.810389.com | www.899852.com | www.233343.com | www.089105.com | www.28je.com | 984268.com | www.680582.com | www.49128.com | www.d48.net | 360994.com | www.655780.com | www.265153.com | www.6169.cc | 568243.com | 567241.com | www.666366.cc | www.088969.com | www.20ma.com | 775555.com | www.587151.com | www.563067.com | www.078926.com | www.xw36.com | 242635.com | www.590337.com | www.079908.com | www.71mp.com | www.bc6.com | www.961956.com | www.130434.com | 502111.com | www.083215.com | hh78.cc | www.810567.com | www.555695.com | www.195549.com | www.98687.cc | www.99zw.com | www.mi4.cc | www.77167s.com | www.892014.com | www.789256.com | www.645488.com | www.524318.com | www.252210.com | www.005013.com | www.721.xyz | www.jf20.com | 861308.com | www.998021.com | www.669321.com | www.389091.com | www.433262.com | www.179921.com | www.59159.com | www.2822.in | www.gn04.com | 946902.com | www.985024.com | www.602107.com | www.259563.com | www.024704.com | www.1511.date | www.ay86.com | 184443.com | www.831103.com | www.500722.cc | www.307179.com | www.041318.com | www.1508.cn | www.wd94.com | 166347.com | www.977335.com | 755395.com | 391589.com | www.960040.com | www.602302.com | www.226186.com | www.022609.com | www.0492.top | www.jv42.com | 286440.com | www.968403.com | www.615516.com | www.383645.com | www.287143.com | www.025632.com | www.1684.tv | www.54si.com | 636015.com | www.965848.com | www.624707.com | www.541155.com | www.363311.com | www.142753.com | www.111017.com | www.5489.cn | www.er56.com | v38.me | www.882767.com | www.766756.com | www.462268.com | www.143145.com | www.99084.com | www.m66.xyz | 190996.com | www.987829.com | www.757577.com | www.416641.com | www.128355.com | www.08836.com | www.pd80.com | 558964.com | www.979069.com | www.717962.com | www.356758.com | www.092653.com | www.2521.org | www.cai1577.com | 262274.com | www.821550.com | www.447774.com | www.321190.com | www.013716.com | www.42951.com | www.zz36.cc | 439975.com | www.903692.com | www.633605.com | www.318099.com | www.96311.cc | www.0182.top | 13e彩票www.963220.com | 9248.biz | www.776819.com | www.396544.com | www.123051.com | www.5228.vip | www.td0.com | 984421.com | www.846608.com | www.495535.com | www.178797.cc | www.014269.com | www.283.red | www.el02.com | 03js.com | 281455.com | www.xc97.com | 492503.com | www.973470.com | www.600469.com | www.208915.com | www.30999.com | www.vx78.com | 380848.com | uf29.com | www.786565.com | www.428160.com | www.064382.com | www.698.cm | 万博彩票www.602266.com | www.096225.com | www.710069.com | www.353134.com | www.81199.cc | www.0330.top | www.cq9.cc | 541110.com | www.869323.com | www.832029.com | www.452811.com | www.077455.com | www.1266.net | 500彩票www.50074e.com | 825558.com | www.679081.com | www.274100.com | www.54685.com | www.220.cx | www.cai550.cc | 686720.com | www.883567.com | www.678655.com | www.365313.cc | www.066130.com | www.802.club | 网易彩票www.502433.com | 044389.com | www.835678.com | www.498355.com | www.087848.com | www.2389.in | www.28gn.com | 145979.com | www.888533.com | www.532228.com | www.139793.com | www.8774.me | www.df68.com | 497234.com | www.801351.com | www.274425.com | www.49242.com | www.66so.com | 021127.com | www.957347.com | www.551383.com | www.167275.com | www.45784.com | www.uy13.com | 012455.com | www.777169.com | www.370128.com | www.289953.com | www.37460.com | www.ir43.com | 90588.com | www.966090.com | www.562127.com | www.278646.com | www.37586.cc | www.iw10.com | 491302.com | www.983703.com | www.777525.com | www.811091.com | 774426.com | www.666862.com | www.739701.com | www.365628.com | www.177095.com | www.62129.cc | www.3794.com | www.846216.com | www.954827.com | www.539310.com | www.125827.com | www.2783.top | 793132.com | www.968730.com | www.550486.com | www.110905.com | www.2030.pro | www.cai744.com | 38228.com | www.810249.com | www.431985.com | www.040592.com | www.44ek.com | 543447.com | www.869278.com | www.822262.com | www.520649.com | www.113771.com | www.0991.me | www.cai0444.com | 334485.com | www.666493.com | www.261387.com | www.20692.com | www.54bu.com | 346841.com | www.907322.com | www.694966.com | www.348756.com | www.69568.cc | www.9bd.com | 548335.com | www.766456.com | www.336866.com | www.44390.com | www.vf24.com | 472345.com | www.740816.com | www.380708.com | www.169228.com | www.032960.com | www.19tp.com | 738485.com | www.803329.com | www.448167.com | www.111012.com | www.5991.xyz | 860943.com | www.974704.com | www.558667.com | www.138809.com | www.8407.loan | www.cai6744.com | 068666.com | www.619657.com | www.256114.com | www.46449.com | www.04lo.com | ek01.com | www.778234.com | www.331251.com | www.30006.cc | www.bn29.com | www.0199957.com | www.616313.cc | www.464494.com | www.026540.com | www.7dj.cc | 801723.com | www.915559.com | www.449989.com | www.025089.com | www.19mn.com | 891552.com | www.808971.com | www.448494.com | www.042807.com | www.16gb.com | 556630.com | www.800484.com | www.326770.com | www.47707.com | www.83fb.com | 155852.com | www.891829.com | www.442198.com | www.189861.com | www.5585.site | 网易彩票www.061wy.com | www.918514.com | www.610227.com | www.550471.com | www.104234.com | www.65vq.com | 469757.com | www.778892.com | www.315388.com | www.11094.com | 99彩票www.858776.com | www.985755.com | www.608499.com | www.143618.com | www.8348.pw | 彩客网www.782478.com | www.964203.com | www.527077.com | www.018991.com | www.f71.pw | 027160.com | www.754898.com | www.301137.com | www.11750.com | 易彩网www.12455h.com | www.954513.com | www.481841.com | www.029857.com | www.l72.net | 534082.com | www.698617.com | www.338369.com | www.071335.com | www.65st.com | 804977.com | www.786308.com | www.361813.com | www.028029.com | www.16vt.com | 554058.com | www.750660.com | www.278117.com | www.7162.win | 乐盈彩票www.88kcw.com | www.866538.com | www.642420.com | www.272392.com | www.10026.com | 大赢家彩票www.591411.com | www.969054.com | www.517930.com | www.025855.com | www.166.bid | 彩客博www.8667a.com | www.929528.com | www.450578.com | www.001354.com | 501836.com | www.947251.com | www.678276.com | www.321017.com | www.44487.cc | www.cai0966.com | www.964524.com | www.581257.com | www.218920.com | www.6340.net | 636092.com | www.900518.com | www.369860.com | www.526249.com | www.829565.com | www.286519.com | www.12540.com | www.vy09.com | 203602.com | www.680971.com | www.311985.com | www.20001.com | 500彩票网www.657505.com | www.990184.com | www.693102.com | www.230693.com | www.36656.cc | www.cp5561.com | www.977633.com | www.559507.com | www.183134.com | www.5307.net | 237947.com | www.948085.com | www.444808.com | www.017092.com | www.d39.cm | 036025.com | www.775412.com | www.684100.com | www.198964.com | www.5850.vip | www.di61.com | 112748.com | www.597601.com | www.120103.com | www.413.red | 167516.com | www.882806.com | www.534349.com | www.033864.com | www.zn16.com | 886684.com | www.599071.com | www.343113.com | www.31923.com | www.cai2341.com | www.988862.com | www.515178.com | www.86181.cc | www.go87.cc | 206519.com | www.769520.com | www.254296.com | www.6480.cm | 850454.com | www.916684.com | www.379836.com | www.92550.cc | www.qw58.com | 399804.com | www.683997.com | www.738796.com | www.183009.com | www.7181.biz | 864683.com | www.749487.com | www.169585.com | www.05536.com | 387744.com | www.820515.com | www.239000.com | www.387.cc | 3464.cc | www.745065.com | www.166024.com | www.0315.in | 607510.com | www.744848.com | www.176422.com | www.1613.xyz | 333272.com | www.715761.com | www.228211.com | www.99jk.com | 579804.com | www.777209.com | www.296001.com | www.22971.cc | www.5981.cn | www.762214.com | www.190496.com | www.44ap.com | 981498.com | www.908050.com | www.691514.com | www.126794.com | www.6375.pw | 872118.com | www.968724.com | www.352707.com | www.7683.top | 080031.com | www.838506.com | www.327753.com | www.09733.com | 061041.com | 287665.com--287665.com | www.722947.com | www.165314.com | www.706.vip | 265927.com | www.730257.com | www.101825.com | www.b27.cn | www.992498.com | www.354747.com | www.6045.shop | 706279.com | www.698483.com | www.130321.com | www.009.cx | 454141.com | www.803691.com | www.197902.com | www.57yc.com | 649448.com | www.529721.com | www.61997.cc | www.en86.com | www.176444.com | www.449892.com | www.64705.com | www.sq44.com | www.949989.com | www.312233.com | www.0137.xyz | 670092.com | www.773251.com | www.148819.com | www.028.me | 732561.com | www.775533.com | www.20hu.com | 585053.com | www.586627.com | www.022794.com | 梦想彩票站www.43131v.com | www.888112.cc | www.314076.com | www.3265.biz | 129924.com | www.566126.com | www.60367.com | www.05ni.com | 778839.com | www.440163.com | www.9063.vip | 618475.com | www.633666.com | www.297255.com | www.1316.vip | 919711.com | www.784201.com | www.166661.com | www.7533.in | 148896.com | www.680692.com | www.191586.com | www.08fz.com | 094234.com | www.436180.com | www.8557.org | 304900.com | www.631965.com | www.024588.com | www.is6.com | www.874688.com | www.606096.com | www.006927.com | www.86wu.com | 06068.com | www.495332.com | www.58852.com | www.a48.top | 567243.com | www.502213.com | 575554.com | www.567047.com | www.020809.com | www.3967.cn | 211909.com | www.707097.com | www.085339.com | www.lx70.com | www.874357.com | www.405139.com | www.92534.com | 财神网www.29277q.com | www.825153.com | www.325844.com | www.25911.cc | 006963.com | www.712675.com | www.094567.com | www.6663.com | 021876.com | www.667682.com | www.029602.com | 中国福利彩票www.3478i.cc | www.767883.com | www.265392.com | www.98xl.com | 470868.com | www.563909.com | www.47085.com | www.9206.vip | 449893.com | www.795522.com | www.327858.com | www.5217.cc | 915538.com | www.641413.com | www.334427.com | www.05125.com | 636205.com | www.912173.com | www.327327.com | www.084883.com | www.3368.pw | 810381.com | www.676903.com | www.314996.com | 450177.com | www.92698.cc | www.778676.com | www.f40.net | www.386597.com | 天下彩www.849689.com | www.191783.com | www.982424.com | www.1578.cc | www.521461.com | 260910.com | www.134689.com | 336566.com | www.8995.xyz | www.627958.com | www.vn55.com | www.300709.com | 809249.com | www.21927.com | 凤凰彩票www.88266x.com | www.231707.com | co36.com | www.9821.loan | www.638156.com | www.08hk.com | www.356894.com | 467214.com | www.117653.com | www.911940.com | www.0033.online | www.587095.com | 539471.com | www.139687.com | 028764.com | www.34939.com | www.682184.com | 彩61www.646880.com | www.181662.com | 6872.biz | www.04835.com | www.656028.com | www.84yt.cc | www.452066.com | 858177.com | www.015629.com | www.821895.com | www.l12.top | www.707511.com | www.bj37.com | www.202335.com | www.984424.com | www.1602.me | www.693149.com | www.hg67.cc | www.333297.com | 895636.com | www.131846.com | www.965768.com | www.290.in | www.626939.com | www.d71.club | www.612080.com | www.918478.com | www.0833.org | www.613228.com | www.cp288.com | www.312789.com | www.jv95.com | www.606586.com | www.uo.com | 844567.com | www.454587.com | www.010030.com | www.cx59.com | www.936893.com | www.377011.com | www.13385.com | 101361.com | www.757882.com | www.120893.com | www.8hm.com | www.979706.com | www.329773.com | www.0791.org | www.527570.com | www.699262.com | www.071068.com | www.fx18.com | www.963770.com | www.301159.com | www.88337.cc | 吉利彩票www.80065k.com | www.831139.com | www.423618.com | www.8814.me | 734562.com | www.597133.com | www.017142.com | 330270.com | www.754863.com | www.105993.com | www.2000.biz | 947920.com | www.739109.com | www.158990.com | www.90lt.cc | 026895.com | www.499166.com | www.24445.cc | 244012.com | www.708911.com | www.127619.com | www.mf85.com | www.944062.com | www.262553.com | www.69jh.com | 333140.com | www.534017.com | www.30144.com | 408722.com | www.692873.com | www.048856.com | www.vw5.com | www.889156.com | www.185761.com | www.80738.com | 500彩票www.50074d.com | www.788532.com | www.106345.com | www.jo92.com | www.874760.com | www.454575.com | www.102711.com | www.pl61.com | www.998340.com | www.300631.com | www.66kf.cc | www.990605.com | www.288553.com | www.289.online | 02iq.com | www.621857.com | www.204163.com | www.86nd.com | www.522822k.com | www.390299.com | www.01305.com | fd08.com | www.629371.com | www.034782.com | 500彩票www.50051x.com | www.791331.com | www.136272.com | www.11mu.com | www.963141.com | www.502350.com | www.186288.com | www.14ob.com | www.990178.com | www.322194.com | www.97pe.com | 871088.com | www.594799.com | www.125437.com | www.18bc.cc | www.980427.com | www.430044.com | www.9734.cc | 642884.com | www.525689.com | www.01050.com | 75650.cc | www.610341.com | www.014328.com | 中彩网www.91233s.com | www.667485.com | www.071399.com | www.cp11.com | www.820928.com | www.268630.com | www.28oc.com | www.927225.com | www.230899.com | www.n89.net | www.902277.com | www.148849.com | www.f98.loan | www.949578.com | www.280890.com | www.07ga.com | www.867358.com | www.432797.com | www.27108.com | 876554.com | www.699786.com | www.054318.com | www.bv99.com | www.826876.com | www.160915.com | www.94tr.com | 981110.com | www.416688.com | www.686916.com | www.057300.com | 手机购彩www.839658.com | www.964948.com | www.304425.com | www.77ya.com | 427714.com | www.395312.com | www.9254.org | 970664.com | www.722212.com | www.327839.com | www.5154.biz | 080480.com | www.466644.com | www.41977.com | 997074.com | www.655512.com | www.286847.com | www.07gc.com | www.978299.com | www.279251.com | www.029971.com | 天天乐彩票www.626310.com | www.780770.com | www.077576.com | www.cai2611.com | www.990269.com | www.314811.com | www.79ku.com | www.990640.com | www.320796.com | www.22161.com | 127679.com | www.623458.com | www.134032.com | www.0hr.com | www.938616.com | www.237306.com | www.xn02.com | www.911087.com | www.201208.com | 通盈彩票www.567388.com | www.816682.com | www.153753.com | www.c85.com | www.950645.com | www.237058.com | www.e60.com | www.020373.com | www.758856.com | www.273579.com | www.21cv.com | www.997363.com | www.651255.com | 521541.com | www.698751.com | www.020139.com | www.cp0305.com | www.777649.com | www.219804.com | www.9cs.cc | www.973985.com | www.254278.com | www.k18.tv | www.911300.com | www.501763.com | www.9713.loan | 82378.com | www.690286.com | www.006721.com | 635566.com | www.703619.com | www.042820.com | www.cp199.com | www.920062.com | www.155374.com | www.778.name | 965843.com | www.500138.com | www.3964.cm | 137745.com | www.493357.com | www.5382.cn | 975943.com | www.666709.com | www.197970.com | www.js91.cc | www.962204.com | www.233921.com | www.yt52.com | www.884983.com | www.216899.com | www.59ea.com | www.986504.com | www.267259.com | www.36lx.com | www.952606.com | www.287935.com | www.53xd.com | www.968554.com | www.233668.com | www.098100.com | www.xj4.com | www.742366.com | www.054044.com | www.cp7656.com | www.765316.com | www.049938.com | www.cp5119.com | www.900078.cc | www.186872.com | www.26499.com | 828617.com | www.654634.com | www.73528.com | E彩堂www.43818v.com | www.671903.com | www.093761.com | www.cai689.com | www.719755.com | www.015763.com | www.93nk.com | cp648.com | www.446132.com | www.005517.com | 263812.com | www.20708.com | www.620923.com | www.ac63.com | www.136936.com | www.948676.com | www.28dj.cc | www.321740.com | 690253.com | www.5760.cc | www.bi51.com | www.123238.com | www.873453.com | www.375706.com | www.9277.net | 127036.com | www.275261.com | www.fg68.com | www.735135.com | www.63369.cc | 162392.com | www.034922.com | www.773447.com | www.g88.live | www.238183.com | www.962455.com | www.70192.com | 456916.com | www.6266.vip | 863834.com | www.628581.com | www.043214.com | www.9872.biz | www.1981.tv | 569234.com | www.518544.com | www.4166.tv | 81bm.com | www.358495.com | www.01711.com | 069260.com | www.463653.com | www.34346.cc | 111732.com | www.426226.com | www.2967.pw | 683908.com | www.555229.com | www.6641.xyz | 531670.com | www.520192.com | www.5479.vip | 647090.com | www.599163.com | www.9877.net | 478329.com--www-955558.com | www.360816.com | www.34561.cc | 466559.com | www.434500.com | www.99fy.cc | 048508.com | www.411211.com | www.8232.cn | 265779.com | www.619732.com | www.006409.com | 137954.com | www.654814.com | www.048471.com | www.17up.com | www.888249.com | www.435211.com | www.3254.xyz | 443997.com | www.388134.com | www.6830.org | 029856.com | www.395514.com | www.3703.win | 892901.com | www.319252.com | 268071.com | www.008061.com | www.702962.com | 彩82www.c6770.com | www.058422.com | www.808516.com | www.mx96.com | www.260891.com | www.970481.com | www.45im.com | www.357627.com | 986841.com | www.9967.net | www.571616.com | www.03uq.com | www.286845.com | www.0566.xyz | 974715.com | www.519040.com | www.23929.cc | 741007.com | www.620869.cc | www.81856.cc | www.146618.com | www.607120.com | www.010390.com | www.401.cn | 984073.com | www.365620.cc | www.6134.me | 499404.com | www.344018.com | www.6516.biz | 312032.com | www.338636.com | www.v53.net | www.891214.com | www.217225.com | www.dz86.com | www.827774.com | www.407472.com | www.9019.org | 577397.com | www.315280.com | www.5fi.com | www.947493.com | www.153535.com | www.wu08.com | www.858352.com | www.227160.com | www.80ai.com | www.917061.com | www.217714.com | www.jy09.com | www.761126.com | www.007061.com | www.948736.com | www.11ky.cc | www.275299.com | www.982599.com | www.385492.com | www.8721.loan | 15886.com | www.244888.cc | www.tp41.com | www.817625.com | www.024150.com | 302751.com | www.623065.com | www.293131.com | www.ry88.com | www.730305.com | www.71620.com | 389241.com | www.626829.com | www.u39.cm | www.321698.com | 640202.com | www.0527.xyz | www.588759.com | 707920.com | www.020994.com | www.966711.com | www.52719.cc | www.911571.com | www.za60.com | www.228316.com | www.920932.com | www.zq10.com | www.205803.com | www.924006.com | www.s32.club | www.219693.com | www.948957.com | www.s50.org | www.243805.com | www.948903.com | www.32lj.com | www.393754.com | www.73kl.com | 525234.com | www.444329.com | www.8201.vip | www.40779.com | www.211687.com | www.74373.com | 彩乐乐www.cll168.com | www.589641.com | www.6446.cn | 512915.com | www.279960.com | www.on41.com | www.863719.com | www.022182.com | 18299.com | www.618106.com | www.100449.com | 35hf.com | www.476688.com | www.69cc.com | www.882017.com | www.271606.com | www.i56.org | www.791804.com | www.97378.com | 106218.com | www.356734.com | www.774.club | www.983149.com | www.251193.com | www.lc99.cc | www.803946.com | www.271878.com | www.pf36.com | www.801310.com | www.87603.com | 294848.com | www.516922.com | www.0038.xyz | 755004.com | www.273187.com | www.ar02.com | www.358049.com | 127185.com | www.7009.wang | www.474676.com | 731051.com | www.5035.biz | 954042.com | www.182400.com | www.942891.com | www.n91.club | www.175845.com | www.881184.com | www.c66.cm | 246873.com | www.234082.com | www.71xg.com | www.893039.com | www.98933.cc | www.681932.com | www.873702.com | www.97553.com | www.900342.com | www.qp06.com | www.158607.com | 345800.com | www.199.top | www.533595.com | 552769.com | www.32672.cc | www.562923.com | 375013.com | www.18970.com | www.548656.com | yd22.com | www.09980.com | www.590111.cc | 698500.com | www.18077.com | www.556904.com | 535024.com | www.9681.xyz | www.491407.com | 324697.com | www.120718.com | www.805999.com | www.cp6936.com | www.084735.com | www.782362.com | www.cai7599.com | www.076826.com | www.731079.com | 盛彩网www.41518q.com | www.020728.com | www.680572.com | www.044177.com | 655584.com | www.ae1.cc | www.755711.com | www.011279.com | www.fq71.com | www.692981.com | www.30846.com | 025084.com | www.273723.com | www.fo60.com | www.833631.com | www.003508.com | 298631.com | www.394877.cc | www.5297.biz | 894794.com | www.284411.com | www.sa49.com | www.799655.com | www.35888.com | 894871.com | www.356625.com | www.099093.com | 347881.com | www.540420.com | www.0199.top | 30891.com--30891.com | www.211819.com | 天天赢彩票www.73736e.com | www.590012.com | www.3439.com | www.860433.com | www.223715.com | www.fo94.com | www.761956.com | www.40503.com | 771564.com | www.380531.com | 中国福利彩票www.34788p.com | www.096699.com | www.768209.com | www.ip14.com | www.281856.com | www.973062.com | www.w90.net | www.226011.com | www.869302.com | www.16666.com | www.530314.com | 447963.com | www.71882.cc | www.cp4